EFFECTS OF BENDING ON THE OPTOELECTRONIC PROPERTIES AND FAILURE MECHANISM IN ORGANIC PHOTOVOLTAICS

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EFFECTS OF BENDING ON THE OPTOELECTRONIC PROPERTIES AND FAILURE MECHANISM IN ORGANIC PHOTOVOLTAICS

Abstract:
Organic photovoltaics (OPVs) have garnered significant attention as a promising renewable energy technology due to their lightweight, flexibility, and potential for low-cost production. However, the mechanical stress induced by bending can significantly impact the optoelectronic properties and overall performance of OPV devices. This abstract highlights the effects of bending on the optoelectronic properties and failure mechanisms in OPVs.

Bending-induced mechanical strain can cause changes in the morphology, structure, and electrical properties of the active layer in OPV devices. Such strain influences the performance parameters, including the power conversion efficiency, open-circuit voltage, short-circuit current density, and fill factor. These changes arise from alterations in charge transport, exciton diffusion, and recombination mechanisms within the organic material upon bending.

The optoelectronic properties affected by bending include the absorption spectrum, light harvesting efficiency, and charge carrier mobility. Bending can induce shifts in the absorption peak, altering the spectral response of the device and affecting its ability to harvest light efficiently. Moreover, mechanical strain can lead to changes in the charge carrier mobility, affecting the transport of electrons and holes within the device, thereby influencing the overall power conversion efficiency.

Furthermore, bending-induced mechanical stress can trigger failure mechanisms in OPVs. These failure mechanisms include cracking, delamination, and electrical breakdown at the interfaces or within the active layer. The development of cracks and delamination can compromise the structural integrity and electrical connectivity of the device, leading to localized dark spots, reduced current flow, and overall device failure.

Understanding the effects of bending on the optoelectronic properties and failure mechanisms in OPVs is crucial for the development of robust and reliable flexible photovoltaic devices. Mitigation strategies such as incorporating flexible substrates, improving material design, and optimizing device architecture can help alleviate the detrimental effects of bending-induced mechanical stress.

In summary, this abstract sheds light on the importance of considering the effects of bending on the optoelectronic properties and failure mechanisms in OPVs. By comprehending these effects and developing strategies to mitigate them, researchers can advance the development of flexible and durable organic photovoltaic devices for sustainable energy applications.

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